Electronic Impurity Doping of Colloidal Semiconductor Nanocrystals

نویسنده

  • Dave Norris
چکیده

Doping is extremely important for controlling the electronic conductivity of bulk semiconductors. However, very few examples exist where impurities that have been incorporated into colloidal semiconductor nanocrystals affect their electronic properties. Here we will discuss the challenges in this area as well as recent progress. In particular, we will describe an approach to lightly dope semiconductor nanocrystals with a controllable amount of electronic impurities. The physical characterization of these materials then shows that the addition of even one impurity per nanocrystal has a dramatic effect on their optical properties. Furthermore, studies of the electrical transport through films of these nanocrystals reveal complex behavior in the Fermi level as a function of dopant concentration. Using techniques to characterize the crystal structure near the impurities, their location within the nanocrystal was determined. These results are consistent with the physical properties and together can explain the observed optical and electrical trends. However, the results also show that dopant behavior in nanocrystals is not as simple as one might expect. Thus, these experiments begin to reveal the properties of a new class of nanocrystal materials that may be important for future nanocrystal devices.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Heavily doped semiconductor nanocrystal quantum dots.

Doping of semiconductors by impurity atoms enabled their widespread technological application in microelectronics and optoelectronics. However, doping has proven elusive for strongly confined colloidal semiconductor nanocrystals because of the synthetic challenge of how to introduce single impurities, as well as a lack of fundamental understanding of this heavily doped limit under strong quantu...

متن کامل

Nonequilibrium-Plasma-Synthesized ZnO Nanocrystals with Plasmon Resonance Tunable via Al Doping and Quantum Confinement.

Metal oxide semiconductor nanocrystals (NCs) exhibit localized surface plasmon resonances (LSPRs) tunable within the infrared (IR) region of the electromagnetic spectrum by vacancy or impurity doping. Although a variety of these NCs have been produced using colloidal synthesis methods, incorporation and activation of dopants in the liquid phase has often been challenging. Herein, using Al-doped...

متن کامل

Influences of Co2+ & Er3+ Co-doping on the Structural and Physical Properties of ZnO Nanocrystals Synthesized by Hydrothermal Route

Co2+ & Er3+ co-doped ZnO nanocrystals were synthesized by the hydrothermal method at 180°C and pH= 12 for 48 h. Powder XRD patterns indicate that the Zn1-2xErxCoxO crystals (0.00<x≤0.035) are isostructural with ZnO. The cell parameters increase for Er3+ and Co2+ upon increasing the dopant content (x). SEM images show that doping of Er3+ and Co2+ into the sites of Zn2+ does not change the morpho...

متن کامل

Influences of Co2+ & Er3+ Co-doping on the Structural and Physical Properties of ZnO Nanocrystals Synthesized by Hydrothermal Route

Co2+ & Er3+ co-doped ZnO nanocrystals were synthesized by the hydrothermal method at 180°C and pH= 12 for 48 h. Powder XRD patterns indicate that the Zn1-2xErxCoxO crystals (0.00<x≤0.035) are isostructural with ZnO. The cell parameters increase for Er3+ and Co2+ upon increasing the dopant content (x). SEM images show that doping of Er3+ and Co2+ into the sites of Zn2+ does not change the morpho...

متن کامل

Doping Semiconductor Nanocrystals: Theory and Experiment

Doping—the intentional introduction of impurities into a material—is fundamental to controlling the properties of bulk semiconductors. The prospect of new technologies has motivated similar efforts to dope semiconductor nanocrystals since their discovery two decades ago. Despite some successes [1–5], many of these efforts have failed, for reasons that remain mysterious. For example, individual ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2012